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Science & Chemistry

Electron Configuration Chart

Compare neutral ground-state configurations, orbital filling order, subshell capacities, noble-gas shorthand, common exceptions, ion configurations, and valence patterns. The chart uses observed configurations where the simple Aufbau prediction and the measured ground state differ.

Electron configuration is a quantum-mechanical orbital-occupancy description. It does not show electrons moving on fixed planetary paths, and introductory filling mnemonics do not replace evaluated ground-state data.

Electron Configuration Chart showing orbital filling order, subshell capacities, noble-gas notation, common exceptions, and ions

How electron configurations work

An electron configuration states how electrons occupy atomic orbitals. IUPAC defines it as the distribution of electrons over one-electron orbitals subject to the Pauli principle. A neutral atom contains the same number of electrons as its atomic number; an ion has fewer electrons when positively charged and more when negatively charged. See the IUPAC definition.

Each orbital holds at most two electrons. An s subshell contains one orbital, p contains three, d contains five, and f contains seven, so their capacities are 2, 6, 10, and 14 electrons. Hund's rule fills equal-energy orbitals singly before pairing, while noble-gas notation shortens the filled inner core.

Meaning

Electrons in orbitals

Electron configuration records how an atom or ion distributes electrons among occupied orbitals and subshells.

Subshell limits

s² · p⁶ · d¹⁰ · f¹⁴

One orbital holds at most two electrons, giving s, p, d, and f capacities of 2, 6, 10, and 14.

Prediction model

Aufbau + Hund + Pauli

These rules build most introductory configurations, but measured ground states include important exceptions.

Short form

[noble gas] + outer electrons

Noble-gas notation replaces a filled inner core with the preceding noble-gas symbol in brackets.

The usual filling sequence correctly predicts many atoms, but chromium is [Ar] 3d⁵ 4s¹ and copper is [Ar] 3d¹⁰ 4s¹. Those are observed neutral ground states, not errors in the table. NIST's evaluated compilation should take priority over a simplified diagonal-rule prediction. See NIST electron configurations.

Electron Configuration Chart for Elements 1–36

Neutral ground-state configurations from hydrogen through krypton. Chromium and copper show observed configurations that differ from the simplest diagonal-filling prediction.

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Neutral ground-state configurations from hydrogen through krypton. Chromium and copper show observed configurations that differ from the simplest diagonal-filling prediction.
ZElementSymbolGround-state configurationNoble-gas notation
1HydrogenH1s¹1s¹
2HeliumHe1s²1s²
3LithiumLi1s² 2s¹[He] 2s¹
4BerylliumBe1s² 2s²[He] 2s²
5BoronB1s² 2s² 2p¹[He] 2s² 2p¹
6CarbonC1s² 2s² 2p²[He] 2s² 2p²
7NitrogenN1s² 2s² 2p³[He] 2s² 2p³
8OxygenO1s² 2s² 2p⁴[He] 2s² 2p⁴
9FluorineF1s² 2s² 2p⁵[He] 2s² 2p⁵
10NeonNe1s² 2s² 2p⁶[He] 2s² 2p⁶
11SodiumNa1s² 2s² 2p⁶ 3s¹[Ne] 3s¹
12MagnesiumMg1s² 2s² 2p⁶ 3s²[Ne] 3s²
13AluminiumAl1s² 2s² 2p⁶ 3s² 3p¹[Ne] 3s² 3p¹
14SiliconSi1s² 2s² 2p⁶ 3s² 3p²[Ne] 3s² 3p²
15PhosphorusP1s² 2s² 2p⁶ 3s² 3p³[Ne] 3s² 3p³
16SulfurS1s² 2s² 2p⁶ 3s² 3p⁴[Ne] 3s² 3p⁴
17ChlorineCl1s² 2s² 2p⁶ 3s² 3p⁵[Ne] 3s² 3p⁵
18ArgonAr1s² 2s² 2p⁶ 3s² 3p⁶[Ne] 3s² 3p⁶
19PotassiumK[Ar] 4s¹[Ar] 4s¹
20CalciumCa[Ar] 4s²[Ar] 4s²
21ScandiumSc[Ar] 3d¹ 4s²[Ar] 3d¹ 4s²
22TitaniumTi[Ar] 3d² 4s²[Ar] 3d² 4s²
23VanadiumV[Ar] 3d³ 4s²[Ar] 3d³ 4s²
24ChromiumCr[Ar] 3d⁵ 4s¹Observed chromium exception[Ar] 3d⁵ 4s¹
25ManganeseMn[Ar] 3d⁵ 4s²[Ar] 3d⁵ 4s²
26IronFe[Ar] 3d⁶ 4s²[Ar] 3d⁶ 4s²
27CobaltCo[Ar] 3d⁷ 4s²[Ar] 3d⁷ 4s²
28NickelNi[Ar] 3d⁸ 4s²[Ar] 3d⁸ 4s²
29CopperCu[Ar] 3d¹⁰ 4s¹Observed copper exception[Ar] 3d¹⁰ 4s¹
30ZincZn[Ar] 3d¹⁰ 4s²[Ar] 3d¹⁰ 4s²
31GalliumGa[Ar] 3d¹⁰ 4s² 4p¹[Ar] 3d¹⁰ 4s² 4p¹
32GermaniumGe[Ar] 3d¹⁰ 4s² 4p²[Ar] 3d¹⁰ 4s² 4p²
33ArsenicAs[Ar] 3d¹⁰ 4s² 4p³[Ar] 3d¹⁰ 4s² 4p³
34SeleniumSe[Ar] 3d¹⁰ 4s² 4p⁴[Ar] 3d¹⁰ 4s² 4p⁴
35BromineBr[Ar] 3d¹⁰ 4s² 4p⁵[Ar] 3d¹⁰ 4s² 4p⁵
36KryptonKr[Ar] 3d¹⁰ 4s² 4p⁶[Ar] 3d¹⁰ 4s² 4p⁶

Superscripts give electron counts in each occupied subshell.

  • These are neutral ground-state configurations.
  • NIST is the reference for observed ground-state configurations; simple filling rules are a model and have exceptions.
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Subshell and Orbital Capacity Chart

Each orbital can hold at most two electrons. The number of orbitals in a subshell determines its total capacity.

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Each orbital can hold at most two electrons. The number of orbitals in a subshell determines its total capacity.
SubshellAngular momentum lOrbitalsMaximum electronsTypical notation
s012
p136p⁶
d2510d¹⁰
f3714f¹⁴

Maximum electrons = 2 × number of orbitals.

  • Pauli exclusion limits each orbital to two electrons with opposite spin.
  • Subshell capacity does not mean every subshell is filled in every ground state.
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Aufbau Orbital Filling Order Chart

The common Aufbau sequence is useful for predicting many ground-state configurations, but observed atomic configurations can differ when subshell energies are very close.

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The common Aufbau sequence is useful for predicting many ground-state configurations, but observed atomic configurations can differ when subshell energies are very close.
StepSubshellCapacityCumulative capacity if filled
11s22
22s24
32p610
43s212
53p618
64s220
73d1030
84p636
95s238
104d1048
115p654
126s256
134f1470
145d1080
156p686
167s288
175f14102
186d10112
197p6118

Sequence used as a practical filling model.

  • Do not use this sequence as proof that every observed ground state follows it exactly.
  • For transition-metal cations, electron removal order is not simply the reverse of this list.
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The superscripts must add to the electron count

Carbon has six electrons, so 1s² 2s² 2p² totals 6. Chloride has 18 electrons because neutral chlorine has 17 and Cl⁻ has gained one. Counting superscripts is the fastest way to catch many configuration mistakes before checking orbital order.

Noble-Gas Core Notation Chart

Bracket notation replaces a completed noble-gas core with its element symbol, making long configurations easier to read.

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Bracket notation replaces a completed noble-gas core with its element symbol, making long configurations easier to read.
CoreAtomic numberFull closed-shell configurationExample use
[He]21s²Li = [He] 2s¹
[Ne]101s² 2s² 2p⁶Na = [Ne] 3s¹
[Ar]18[Ne] 3s² 3p⁶Fe = [Ar] 3d⁶ 4s²
[Kr]36[Ar] 3d¹⁰ 4s² 4p⁶Mo = [Kr] 4d⁵ 5s¹
[Xe]54[Kr] 4d¹⁰ 5s² 5p⁶Au = [Xe] 4f¹⁴ 5d¹⁰ 6s¹
[Rn]86[Xe] 4f¹⁴ 5d¹⁰ 6s² 6p⁶Used as the core for many actinides

Bracketed symbol means all electrons of that noble-gas ground-state core are included.

  • Use the preceding noble gas, not the nearest noble gas after the element.
  • NIST uses bracketed rare-gas symbols to shorten heavier configurations.
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Common Ground-State Configuration Exceptions

Several atoms have observed ground states that differ from the simplest Aufbau prediction because nearby subshells have similar energies.

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Several atoms have observed ground states that differ from the simplest Aufbau prediction because nearby subshells have similar energies.
ElementSimple predictionObserved ground statePattern to remember
Chromium (Cr)[Ar] 3d⁴ 4s²[Ar] 3d⁵ 4s¹Half-filled 3d in the observed ground state
Copper (Cu)[Ar] 3d⁹ 4s²[Ar] 3d¹⁰ 4s¹Filled 3d in the observed ground state
Niobium (Nb)[Kr] 4d³ 5s²[Kr] 4d⁴ 5s¹Observed redistribution between 4d and 5s
Molybdenum (Mo)[Kr] 4d⁴ 5s²[Kr] 4d⁵ 5s¹Half-filled 4d
Ruthenium (Ru)[Kr] 4d⁶ 5s²[Kr] 4d⁷ 5s¹Observed 4d/5s redistribution
Rhodium (Rh)[Kr] 4d⁷ 5s²[Kr] 4d⁸ 5s¹Observed 4d/5s redistribution
Palladium (Pd)[Kr] 4d⁸ 5s²[Kr] 4d¹⁰Filled 4d; 5s is empty in the ground state
Platinum (Pt)[Xe] 4f¹⁴ 5d⁸ 6s²[Xe] 4f¹⁴ 5d⁹ 6s¹Observed 5d/6s redistribution
Gold (Au)[Xe] 4f¹⁴ 5d⁹ 6s²[Xe] 4f¹⁴ 5d¹⁰ 6s¹Filled 5d in the observed ground state

Observed neutral ground-state configurations.

  • Treat these as observed configurations, not as a universal “half-filled/full-filled rule.”
  • Heavier atoms can require more detailed relativistic and spectroscopic treatment.
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Aufbau is a model, not an exception-free law

Subshell energies can be close enough that the lowest-energy many-electron arrangement differs from the simplest mnemonic. NIST lists chromium as [Ar] 3d⁵ 4s¹, copper as [Ar] 3d¹⁰ 4s¹, palladium as [Kr] 4d¹⁰, platinum as [Xe] 4f¹⁴ 5d⁹ 6s¹, and gold as [Xe] 4f¹⁴ 5d¹⁰ 6s¹.

Electron Configuration Finder

Choose atomic number 1–36 to see the observed neutral ground-state configuration used by this chart. Chromium and copper use their measured ground-state exceptions rather than the simplest Aufbau prediction.

Z = 24

Chromium (Cr)

Ground-state configuration
[Ar] 3d⁵ 4s¹
Noble-gas notation
[Ar] 3d⁵ 4s¹
Electrons by principal shell
2, 8, 13, 1
Electrons outside listed noble-gas core
6

The finder reports neutral atoms only. Ion configurations require adding or removing electrons from the neutral ground state using ion-specific rules.

Common Ion Electron Configuration Chart

Main-group ions often reach a noble-gas configuration. Transition-metal cations generally lose the outer ns electrons before electrons from the (n−1)d subshell.

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Main-group ions often reach a noble-gas configuration. Transition-metal cations generally lose the outer ns electrons before electrons from the (n−1)d subshell.
SpeciesNeutral atomElectrons added / removedIon configuration
Na⁺[Ne] 3s¹Remove 1 from 3s[Ne]
Mg²⁺[Ne] 3s²Remove 2 from 3s[Ne]
Al³⁺[Ne] 3s² 3p¹Remove 3 from n = 3[Ne]
O²⁻[He] 2s² 2p⁴Add 2 to 2p[Ne]
Cl⁻[Ne] 3s² 3p⁵Add 1 to 3p[Ar]
Ca²⁺[Ar] 4s²Remove 2 from 4s[Ar]
Cr³⁺[Ar] 3d⁵ 4s¹Remove 4s¹, then 2 from 3d[Ar] 3d³
Mn²⁺[Ar] 3d⁵ 4s²Remove 2 from 4s[Ar] 3d⁵
Fe²⁺[Ar] 3d⁶ 4s²Remove 2 from 4s[Ar] 3d⁶
Fe³⁺[Ar] 3d⁶ 4s²Remove 2 from 4s, then 1 from 3d[Ar] 3d⁵
Cu⁺[Ar] 3d¹⁰ 4s¹Remove 1 from 4s[Ar] 3d¹⁰
Cu²⁺[Ar] 3d¹⁰ 4s¹Remove 4s¹, then 1 from 3d[Ar] 3d⁹
Zn²⁺[Ar] 3d¹⁰ 4s²Remove 2 from 4s[Ar] 3d¹⁰

Ground-state electron counts for common monatomic ions.

  • For transition metals, remove electrons from the highest principal quantum number ns subshell before (n−1)d.
  • An ion configuration is not obtained by blindly reversing the neutral filling sequence.
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Transition-metal ions lose ns electrons before (n−1)d electrons

Iron is [Ar] 3d⁶ 4s², but Fe²⁺ is [Ar] 3d⁶ because the two 4s electrons are removed first. Fe³⁺ is then [Ar] 3d⁵. Copper follows the same removal logic from its observed neutral ground state: Cu⁺ is [Ar] 3d¹⁰ and Cu²⁺ is [Ar] 3d⁹.

Orbital Box Rules Chart

Orbital diagrams add electron spin and orbital occupancy to the configuration notation.

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Orbital diagrams add electron spin and orbital occupancy to the configuration notation.
RuleMeaningExampleCommon mistake
Pauli exclusionMaximum two electrons per orbital with opposite spins1s² = ↑↓Putting three electrons in one orbital
Hund ruleFill degenerate orbitals singly before pairing2p³ = ↑ ↑ ↑Pairing in one p orbital too early
Aufbau principleOccupy lower-energy orbitals first as a starting model1s before 2s before 2pAssuming the simple order has no exceptions
Electron countSuperscripts must sum to the species electron totalFe: 26 electronsForgetting ionic charge changes electron count
Degeneracyp, d, f contain 3, 5, 7 orbitals respectivelyd has five boxesDrawing one box for an entire d subshell

Arrow direction represents spin projection in orbital-box notation.

  • Orbital boxes are a representation of one-electron orbitals and occupancies, not literal electron paths.
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Main-Group Valence Configuration Patterns

For representative main-group elements, the outer-shell ns and np pattern tracks the group and helps predict common bonding behavior.

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For representative main-group elements, the outer-shell ns and np pattern tracks the group and helps predict common bonding behavior.
GroupOuter configuration patternTypical valence electronsExample
1ns¹1Na: [Ne] 3s¹
2ns²2Mg: [Ne] 3s²
13ns² np¹3Al: [Ne] 3s² 3p¹
14ns² np²4Si: [Ne] 3s² 3p²
15ns² np³5P: [Ne] 3s² 3p³
16ns² np⁴6S: [Ne] 3s² 3p⁴
17ns² np⁵7Cl: [Ne] 3s² 3p⁵
18ns² np⁶8Ar: [Ne] 3s² 3p⁶

Helium is the main exception to the ns²np⁶ noble-gas pattern because its shell contains only 1s².

  • Transition-metal valence counting is more context dependent because both ns and (n−1)d electrons can participate in chemistry.
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Principal Shell Capacity and Subshell Chart

A principal shell with quantum number n can contain up to 2n² electrons, but ground-state atoms do not simply fill one shell completely before beginning the next.

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A principal shell with quantum number n can contain up to 2n² electrons, but ground-state atoms do not simply fill one shell completely before beginning the next.
Shell nAvailable subshellsMaximum shell capacity 2n²Important note
11s2Only the s subshell exists
22s, 2p8Second-period elements fill these subshells
33s, 3p, 3d184s begins filling before 3d in the common Aufbau sequence
44s, 4p, 4d, 4f32Several n = 4 subshells fill across different periods
55s, 5p, 5d, 5f, 5g50The g subshell is part of the mathematical shell even though ordinary ground-state tables focus on lower-l subshells
66s, 6p, 6d, 6f, 6g, 6h72Known ground states use only part of this mathematical capacity
77s, 7p, 7d, 7f, 7g, 7h, 7i98High-n orbital ordering becomes increasingly complex

Maximum capacity of a complete principal shell = 2n².

  • The 2n² rule is a shell capacity rule, not a step-by-step filling order.
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Common Electron Configuration Errors and Corrections

Most configuration errors come from incorrect electron totals, subshell capacities, ion removal order, or treating the Aufbau sequence as exception free.

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Most configuration errors come from incorrect electron totals, subshell capacities, ion removal order, or treating the Aufbau sequence as exception free.
MistakeWhy it failsBetter approach
Write p⁷A p subshell has only three orbitals and holds at most six electronsMove the next electron to the next available subshell
Write d¹¹A d subshell has five orbitals and holds at most ten electronsRespect the d¹⁰ capacity
Use [Ar] 3d⁴ 4s² for chromiumThat is the simplest prediction, not the observed neutral ground stateUse [Ar] 3d⁵ 4s¹
Use [Ar] 3d⁹ 4s² for copperThat is not the observed neutral ground stateUse [Ar] 3d¹⁰ 4s¹
Remove 3d electrons before 4s for Fe²⁺Transition-metal cations lose the higher-n 4s electrons firstFe²⁺ = [Ar] 3d⁶
Forget charge when counting electronsIons do not have Z electrons unless neutralElectron count = Z − positive charge or Z + magnitude of negative charge
Choose the next noble gas in shorthandThat would include electrons the atom does not haveUse the preceding noble-gas core
Treat orbital boxes as electron trajectoriesOrbitals are quantum states, not little planetary pathsUse boxes only to represent occupancy and spin
Call every outer-shell electron “the only valence electron” in transition metalsd electrons can participate in transition-metal chemistryState the valence convention being used
Assume excited-state configurations equal ground statesPromoted electrons describe a different electronic stateLabel excited states explicitly

Checklist for neutral atoms, ions, and orbital diagrams.

  • When a reference table and a simple mnemonic disagree, use evaluated observed ground-state data for the atom in question.
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Ground state and excited state are not interchangeable

A ground-state configuration gives the lowest-energy arrangement for the specified species. An excited state promotes one or more electrons into a higher-energy orbital. When a problem asks for the electron configuration without another qualifier, use the ground state unless the context explicitly describes excitation.

NIST's periodic table incorporates critically evaluated atomic data including ground-state configurations, which makes it a stronger reference than a hand-drawn diagonal mnemonic when exact configurations matter. See the NIST periodic table reference.

Frequently asked questions

What is an electron configuration?

An electron configuration describes how electrons are distributed among atomic orbitals. The superscripts show how many electrons occupy each subshell.

How many electrons fit in s, p, d, and f subshells?

An s subshell holds 2 electrons, p holds 6, d holds 10, and f holds 14.

What is the Aufbau filling order?

A common sequence is 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p. Observed ground states include exceptions.

Why is chromium [Ar] 3d5 4s1?

The observed chromium ground state is [Ar] 3d⁵ 4s¹ rather than the simplest [Ar] 3d⁴ 4s² prediction because the 3d and 4s energies are close and the actual many-electron ground state is lower in energy.

Why is copper [Ar] 3d10 4s1?

Copper has the observed ground-state configuration [Ar] 3d¹⁰ 4s¹. It is another case where the simplest diagonal-filling prediction does not match the measured ground state.

What does noble-gas notation mean?

Noble-gas notation replaces the filled inner-shell configuration with the symbol of the preceding noble gas in brackets, such as Fe = [Ar] 3d⁶ 4s².

How do I find the electron configuration of an ion?

Start from the neutral ground-state configuration, adjust the electron count for charge, and remove or add electrons using the correct orbital order for that ion.

Why are 4s electrons removed before 3d electrons?

Although 4s is occupied before 3d in the usual neutral-atom filling sequence, transition-metal cations generally lose the higher-principal-quantum-number 4s electrons before 3d electrons.

What is Hund rule?

Hund rule says degenerate orbitals are occupied singly with parallel spin before electrons pair in the same orbital.

What is the Pauli exclusion principle?

No two electrons in one atom can have the same complete set of quantum numbers, so one orbital holds at most two electrons with opposite spin.

How many orbitals are in p, d, and f subshells?

A p subshell has 3 orbitals, d has 5, and f has 7.

How do I check an electron configuration?

Add every superscript and confirm the total equals the species electron count, then verify subshell capacities and any known ground-state exception.

Are valence electrons always the electrons in the highest shell?

That shortcut works well for many main-group elements, but transition-metal chemistry can also involve electrons from the partially filled d subshell.

Is the Aufbau rule exact?

No. It is a useful orbital-filling model, but evaluated ground-state configurations show multiple exceptions where near-degenerate subshells redistribute electrons.

Does an electron configuration show where an electron physically is?

No. It specifies orbital occupancy in a quantum-mechanical description; it does not trace a classical path around the nucleus.

What is an excited-state electron configuration?

An excited-state configuration has one or more electrons promoted above the ground-state arrangement. It must be identified separately from the ground state.

Use the Atomic Radius Chart to connect electronic structure with periodic size trends, the Codon Chart for molecular-biology notation, or the Density Chart for physical-property reference data.

Sources

International Union of Pure and Applied ChemistryGold Book — electron configuration

Defines electron configuration as the distribution of electrons over one-electron orbitals subject to the Pauli principle.

https://goldbook.iupac.org/terms/view/C01248

National Institute of Standards and TechnologyElectronic Configurations of the Elements

Provides evaluated neutral ground-state electron configurations and first-cation configurations for elements through uranium.

https://www.nist.gov/pml/atomic-reference-data-electronic-structure-calculations/atomic-reference-data-electronic-8

National Institute of Standards and TechnologyPeriodic Table of the Elements

NIST periodic table with critically evaluated atomic data including ground-state configuration.

https://www.nist.gov/publications/periodic-table-elements-0

National Institute of Standards and TechnologyGround Levels and Ionization Energies for the Neutral Atoms

Explains NIST ground-state configuration notation and noble-gas abbreviation in atomic data tables.

https://www.nist.gov/pml/ground-levels-and-ionization-energies-neutral-atoms